Mister Freeze

Few villains in the DC universe carry the chilling menace of Mister Freeze, who made his Copper Age debut in Super Powers #4 (1986) under the creative hands of Paul Kupperberg and the legendary Carmine Infantino. Over the span of four decades, he's carved out a formidable presence across the pages of Detective Comics and Batman, the very heart of the Dark Knight's world, sharing those shadowy Gotham streets with the likes of Robin, Batgirl, Dick Grayson, Barbara Gordon, and Catwoman. With 82 catalog appearances and a key issue to his name, Freeze is no mere footnote — he's a recurring, collector-worthy fixture in Batman's rogues gallery whose icy grip on readers has never loosened.